2) Peter Parker and Mary Jane Watson (Spider-Man 1 – 3)
Sam Raimi’s Spider-Man movies were more romantic than most superhero films, as just as much of their runtime was dedicated to the ups and downs of Peter’s relationship with MJ as it was his fights against Green Goblin, Doc Ock and the like.
And there were a heck of a lot of ups and downs. Throughout those three movies, there are various love triangles, abandoned marriages and even some awkward jazz dancing. You might wish that the pair would just settle down and stay together but that’s the story of this version of the characters – they are destined to be together, but fate keeps intervening. As this list proves, the path of true love never runs smooth for a superhero, after all.
The couple also have possibly the single most iconic romantic moment in superhero movies – the famous upside down kiss in the rain from the first movie.